Assembled Lanthanide Complexes with Advanced Photophysical Properties

Nonfiction, Science & Nature, Science, Chemistry, Inorganic, Organic
Cover of the book Assembled Lanthanide Complexes with Advanced Photophysical Properties by Yuichi Hirai, Springer Singapore
View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart
Author: Yuichi Hirai ISBN: 9789811089329
Publisher: Springer Singapore Publication: April 7, 2018
Imprint: Springer Language: English
Author: Yuichi Hirai
ISBN: 9789811089329
Publisher: Springer Singapore
Publication: April 7, 2018
Imprint: Springer
Language: English

This thesis provides essential information on the systematic design of assembled lanthanide complexes for functional luminescent materials. It discusses the relationships between assembled structures and photo, thermal, and mechanical properties on the basis of crystallography, spectroscopy, and thermodynamics. The described guidelines for assembled structures will be extremely valuable, both for industrial applications and for readers’ fundamental understanding of solid-state photophysics and materials chemistry.

Luminescent lanthanide complexes are promising candidates for lighting devices, lasers, and bio-probes owing to their line-like and long-lived emission arising from characteristic 4f–4f transitions. Low-vibrational and asymmetrical coordination structures around lanthanide ions have been introduced to achieve strong luminescence, using specific organic ligands. Recently, assembled lanthanide complexes including coordination polymers and metal organic frameworks have increasingly attracted attention as a new class of luminescent materials offering thermal stability and color tunability. However, improving the luminescence efficiencies of these compounds remains a challenge, and specific molecular designs to control assembled structures and yield additional physical properties have not been established. The author provides a group of bent-angled bridging ligands to boost photoluminescence efficiency, and successfully introduces for the first time glass formability and strong triboluminescence properties.

View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart

This thesis provides essential information on the systematic design of assembled lanthanide complexes for functional luminescent materials. It discusses the relationships between assembled structures and photo, thermal, and mechanical properties on the basis of crystallography, spectroscopy, and thermodynamics. The described guidelines for assembled structures will be extremely valuable, both for industrial applications and for readers’ fundamental understanding of solid-state photophysics and materials chemistry.

Luminescent lanthanide complexes are promising candidates for lighting devices, lasers, and bio-probes owing to their line-like and long-lived emission arising from characteristic 4f–4f transitions. Low-vibrational and asymmetrical coordination structures around lanthanide ions have been introduced to achieve strong luminescence, using specific organic ligands. Recently, assembled lanthanide complexes including coordination polymers and metal organic frameworks have increasingly attracted attention as a new class of luminescent materials offering thermal stability and color tunability. However, improving the luminescence efficiencies of these compounds remains a challenge, and specific molecular designs to control assembled structures and yield additional physical properties have not been established. The author provides a group of bent-angled bridging ligands to boost photoluminescence efficiency, and successfully introduces for the first time glass formability and strong triboluminescence properties.

More books from Springer Singapore

Cover of the book Classroom Writing Assessment and Feedback in L2 School Contexts by Yuichi Hirai
Cover of the book The Meaning of Citizenship in Contemporary Chinese Society by Yuichi Hirai
Cover of the book Advances in Soil Microbiology: Recent Trends and Future Prospects by Yuichi Hirai
Cover of the book Public-Private Partnerships in Infrastructure by Yuichi Hirai
Cover of the book Corporate Social Responsibility in India by Yuichi Hirai
Cover of the book Total Urban Mobilisation by Yuichi Hirai
Cover of the book Recent Trends in Communication, Computing, and Electronics by Yuichi Hirai
Cover of the book International Communication Strategies of Chinese Radio and TV Networks by Yuichi Hirai
Cover of the book University Social Responsibility and Quality of Life by Yuichi Hirai
Cover of the book Residual Stresses and Nanoindentation Testing of Films and Coatings by Yuichi Hirai
Cover of the book Teacher Empowerment Toward Professional Development and Practices by Yuichi Hirai
Cover of the book Futuristic Trends in Network and Communication Technologies by Yuichi Hirai
Cover of the book Energy Relations and Policy Making in Asia by Yuichi Hirai
Cover of the book Keynesian Macroeconomics Beyond the IS-LM Model by Yuichi Hirai
Cover of the book Knowledge Computing and Its Applications by Yuichi Hirai
We use our own "cookies" and third party cookies to improve services and to see statistical information. By using this website, you agree to our Privacy Policy