Mechanisms of Polymer Degradation and Stabilisation

Nonfiction, Science & Nature, Technology, Textiles & Polymers, Material Science
Cover of the book Mechanisms of Polymer Degradation and Stabilisation by , Springer Netherlands
View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart
Author: ISBN: 9789401138383
Publisher: Springer Netherlands Publication: December 6, 2012
Imprint: Springer Language: English
Author:
ISBN: 9789401138383
Publisher: Springer Netherlands
Publication: December 6, 2012
Imprint: Springer
Language: English

The purpose of this publication is two-fold. In the first place it is intended to review progress in the development of practical stabilising systems for a wide range of polymers and applications. A complemen­ tary and ultimately more important objective is to accommodate these practical developments within the framework of antioxidant theory, since there can be little question that further major advances in the practice of stabilisation technology will only be possible on a firm mechanistic foundation. With the continual increase in the number of commercial anti­ oxidants and stabilisers, often functioning by mechanisms not even considered ten years ago, there is a need for a general theory which will allow the potential user to predict the performance of a particular antioxidant structure under specific practical conditions. Any such predictive tool must involve a simplified kinetic approach to inhibited oxidation and, in Chapter 1, Denisov outlines a possible mechanistic approach with the potential to predict the most useful antioxidant to use and the limits of its usefulness. In Chapter 2, Schwetlick reviews the current state of knowledge on the antioxidant mechanisms of the phosphite esters with particular emphasis on their catalytic peroxidolytic activity. Dithiophosphate v vi PREFACE derivatives show a similar behaviour but for quite different reasons and, in Chapter 3, AI-Malaika reviews information available from analytical studies, particularly using 31p_NMR spectroscopy, to elucid­ ate the complex chemistry that leads to the formation of the antioxidant -active agents.

View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart

The purpose of this publication is two-fold. In the first place it is intended to review progress in the development of practical stabilising systems for a wide range of polymers and applications. A complemen­ tary and ultimately more important objective is to accommodate these practical developments within the framework of antioxidant theory, since there can be little question that further major advances in the practice of stabilisation technology will only be possible on a firm mechanistic foundation. With the continual increase in the number of commercial anti­ oxidants and stabilisers, often functioning by mechanisms not even considered ten years ago, there is a need for a general theory which will allow the potential user to predict the performance of a particular antioxidant structure under specific practical conditions. Any such predictive tool must involve a simplified kinetic approach to inhibited oxidation and, in Chapter 1, Denisov outlines a possible mechanistic approach with the potential to predict the most useful antioxidant to use and the limits of its usefulness. In Chapter 2, Schwetlick reviews the current state of knowledge on the antioxidant mechanisms of the phosphite esters with particular emphasis on their catalytic peroxidolytic activity. Dithiophosphate v vi PREFACE derivatives show a similar behaviour but for quite different reasons and, in Chapter 3, AI-Malaika reviews information available from analytical studies, particularly using 31p_NMR spectroscopy, to elucid­ ate the complex chemistry that leads to the formation of the antioxidant -active agents.

More books from Springer Netherlands

Cover of the book Colour Vision Deficiencies IX by
Cover of the book Making Teaching and Learning Matter by
Cover of the book Stereochemical Analysis of Alicyclic Compounds by C-13 NMR Spectroscopy by
Cover of the book Natural Hazard Mitigation Policy by
Cover of the book Non-Renewable Resource Issues by
Cover of the book Cancer Management in Man: Chemotherapy, Biological Therapy, Hyperthermia and Supporting Measures by
Cover of the book Nutrition and Heart Disease by
Cover of the book Molecular Genetics in Fisheries by
Cover of the book Variation-Aware Adaptive Voltage Scaling for Digital CMOS Circuits by
Cover of the book Language and Illumination by
Cover of the book Secondary Analysis of the TIMSS Data by
Cover of the book Drugs and the Liver: High Risk Patients and Transplantation by
Cover of the book Trends in Levels and Effects of Persistent Toxic Substances in the Great Lakes by
Cover of the book The Mediterranean Sea by
Cover of the book Private or Socialistic Forestry? by
We use our own "cookies" and third party cookies to improve services and to see statistical information. By using this website, you agree to our Privacy Policy