The Double [3+2] Photocycloaddition Reaction

Nonfiction, Science & Nature, Science, Chemistry, Clinical, Organic
Cover of the book The Double [3+2] Photocycloaddition Reaction by Jason A. Woolford, Springer Berlin Heidelberg
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Author: Jason A. Woolford ISBN: 9783642228605
Publisher: Springer Berlin Heidelberg Publication: August 30, 2011
Imprint: Springer Language: English
Author: Jason A. Woolford
ISBN: 9783642228605
Publisher: Springer Berlin Heidelberg
Publication: August 30, 2011
Imprint: Springer
Language: English

Jason Woolford's thesis describes for the first time, a double [3+2] photocycloaddition of alkenes onto aromatic rings. Modern synthetic chemistry relies on the ability of researchers to uncover new and more efficient ways of creating highly complex structures. This work describes a novel, environmentally friendly photochemical step that converts in one pot, trivial starting materials into otherwise difficult to construct fenstrane frameworks.  The rigid cores of these frameworks have significant potential in drug design. Moreover, the novelty of this work overtakes many other methods for the creation of chiral centres. No less than seven chiral centres are created in the photochemical step together with the formation of four carbon-carbon bonds  and multifused rings. Jason's innovative work has been the subject of several publications in peer-reviewed journals.

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Jason Woolford's thesis describes for the first time, a double [3+2] photocycloaddition of alkenes onto aromatic rings. Modern synthetic chemistry relies on the ability of researchers to uncover new and more efficient ways of creating highly complex structures. This work describes a novel, environmentally friendly photochemical step that converts in one pot, trivial starting materials into otherwise difficult to construct fenstrane frameworks.  The rigid cores of these frameworks have significant potential in drug design. Moreover, the novelty of this work overtakes many other methods for the creation of chiral centres. No less than seven chiral centres are created in the photochemical step together with the formation of four carbon-carbon bonds  and multifused rings. Jason's innovative work has been the subject of several publications in peer-reviewed journals.

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