Chemistry of Thioamides

Nonfiction, Science & Nature, Science, Chemistry, Technical & Industrial, Organic
Cover of the book Chemistry of Thioamides by , Springer Singapore
View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart
Author: ISBN: 9789811378287
Publisher: Springer Singapore Publication: May 14, 2019
Imprint: Springer Language: English
Author:
ISBN: 9789811378287
Publisher: Springer Singapore
Publication: May 14, 2019
Imprint: Springer
Language: English

This book covers whole aspects of the sulfur isologues of amides. Starting from the synthetic methods of thioamides, a range of synthetic applications to the construction of carbon–sulfur and carbon–carbon bonds, to asymmetric reactions, to formation of heterocycles are described.

Among the array of thiocarbonyl compounds, thioamides are readily handled in room temperature air. Some of their characteristic features are that the polarity of C=S bonds in thioamides is much smaller than C=O bonds in ordinary amides, that thioamides possess higher HOMO and lower LUMO when compared with those of ordinary amides, and that carbon atoms alpha to the C=S and nitrogen atoms in thioamides are more acidic than those in ordinary amides. Theoretical studies further disclose their features.

Thioamides are also used as ligands to a wide variety of metals. Their unique photophysical properties and catalytic activities are described here. Characteristic features of biologically relevant thioamides, e.g., thiopeptides and related compounds, are the final focus of the book. 

View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart

This book covers whole aspects of the sulfur isologues of amides. Starting from the synthetic methods of thioamides, a range of synthetic applications to the construction of carbon–sulfur and carbon–carbon bonds, to asymmetric reactions, to formation of heterocycles are described.

Among the array of thiocarbonyl compounds, thioamides are readily handled in room temperature air. Some of their characteristic features are that the polarity of C=S bonds in thioamides is much smaller than C=O bonds in ordinary amides, that thioamides possess higher HOMO and lower LUMO when compared with those of ordinary amides, and that carbon atoms alpha to the C=S and nitrogen atoms in thioamides are more acidic than those in ordinary amides. Theoretical studies further disclose their features.

Thioamides are also used as ligands to a wide variety of metals. Their unique photophysical properties and catalytic activities are described here. Characteristic features of biologically relevant thioamides, e.g., thiopeptides and related compounds, are the final focus of the book. 

More books from Springer Singapore

Cover of the book Design, Synthesis and Applications of One-Dimensional Chalcogenide Hetero-Nanostructures by
Cover of the book Groundwater of South Asia by
Cover of the book Quadrilingual Education in Singapore by
Cover of the book A Study into the Design of Steerable Microphone Arrays by
Cover of the book The Story of Indian Manufacturing by
Cover of the book Electrochemistry for Corrosion Fundamentals by
Cover of the book Copyright and Fan Productivity in China by
Cover of the book Advances in Manufacturing Processes by
Cover of the book Recent Trends in Physics of Material Science and Technology by
Cover of the book Communication, Culture and Ecology by
Cover of the book Silviculture of South Asian Priority Bamboos by
Cover of the book Business Cycle Dynamics and Stabilization Policies by
Cover of the book Eco-friendly Agro-biological Techniques for Enhancing Crop Productivity by
Cover of the book Energy Engineering by
Cover of the book Researching and Teaching Second Language Speech Acts in the Chinese Context by
We use our own "cookies" and third party cookies to improve services and to see statistical information. By using this website, you agree to our Privacy Policy