Organometallics for Green Catalysis

Nonfiction, Science & Nature, Science, Chemistry, Technical & Industrial, General Chemistry
Cover of the book Organometallics for Green Catalysis by , Springer International Publishing
View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart
Author: ISBN: 9783030109554
Publisher: Springer International Publishing Publication: February 25, 2019
Imprint: Springer Language: English
Author:
ISBN: 9783030109554
Publisher: Springer International Publishing
Publication: February 25, 2019
Imprint: Springer
Language: English

This volume presents the latest developments in the use of organometallic catalysis for the formation of bulk chemicals and the production of energy, via green processes including efficient utilization of waste feedstocks from industry. The chemistry of carbon dioxide relating to its hydrogenation into methanol –an eco-friendly energy storage strategy– and its uses as C1 synthon for the formation of important building-blocks for fine chemicals industry are covered. Catalytic hydrogenations of various functional groups and hydrogen transfer reactions including the use of first row metal catalysts are presented as well as the conversion of alcohols to carboxylates via hydrogen transfer with a zero-waste strategy using water. Transformation of renewable or bio-based raw materials is surveyed through alkene metathesis and C–O bond activations and functionalizations. A green aspect for selective formation of C-C, C-O and C-N bonds involves direct regioselective C–H bond activations and functionalizations. These transformations can now be promoted under mild reaction conditions due to the use photoredox catalyts. C–H bond oxidation using visible light leads mainly to the formation of C–O and C–N bonds, whereas cross-coupled C–C bonds can be formed through the radical additions on (hetero) arenes using photoredox assisted mechanism.

View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart

This volume presents the latest developments in the use of organometallic catalysis for the formation of bulk chemicals and the production of energy, via green processes including efficient utilization of waste feedstocks from industry. The chemistry of carbon dioxide relating to its hydrogenation into methanol –an eco-friendly energy storage strategy– and its uses as C1 synthon for the formation of important building-blocks for fine chemicals industry are covered. Catalytic hydrogenations of various functional groups and hydrogen transfer reactions including the use of first row metal catalysts are presented as well as the conversion of alcohols to carboxylates via hydrogen transfer with a zero-waste strategy using water. Transformation of renewable or bio-based raw materials is surveyed through alkene metathesis and C–O bond activations and functionalizations. A green aspect for selective formation of C-C, C-O and C-N bonds involves direct regioselective C–H bond activations and functionalizations. These transformations can now be promoted under mild reaction conditions due to the use photoredox catalyts. C–H bond oxidation using visible light leads mainly to the formation of C–O and C–N bonds, whereas cross-coupled C–C bonds can be formed through the radical additions on (hetero) arenes using photoredox assisted mechanism.

More books from Springer International Publishing

Cover of the book Business Challenges in the Changing Economic Landscape - Vol. 1 by
Cover of the book Leptin by
Cover of the book Agents and Artificial Intelligence by
Cover of the book Piezo-Electric Electro-Acoustic Transducers by
Cover of the book Biotechnology in Africa by
Cover of the book Atlas of Cardiac Innervation by
Cover of the book Computational Intelligence in Analog and Mixed-Signal (AMS) and Radio-Frequency (RF) Circuit Design by
Cover of the book Advances in Luxury Brand Management by
Cover of the book Lobar Approach to Breast Ultrasound by
Cover of the book AI*IA 2016 Advances in Artificial Intelligence by
Cover of the book Computational and Experimental Biomedical Sciences: Methods and Applications by
Cover of the book Machining of Bone and Hard Tissues by
Cover of the book Assessment and Teaching of 21st Century Skills by
Cover of the book Publicly Funded Transport Research in the P. R. China, Japan, and Korea by
Cover of the book Emotion in Organizational Change by
We use our own "cookies" and third party cookies to improve services and to see statistical information. By using this website, you agree to our Privacy Policy