Development of New Catalytic Performance of Nanoporous Metals for Organic Reactions

Nonfiction, Science & Nature, Science, Chemistry, Organic, Technical & Industrial
Cover of the book Development of New Catalytic Performance of Nanoporous Metals for Organic Reactions by Mei Yan, Springer Japan
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Author: Mei Yan ISBN: 9784431549314
Publisher: Springer Japan Publication: March 24, 2014
Imprint: Springer Language: English
Author: Mei Yan
ISBN: 9784431549314
Publisher: Springer Japan
Publication: March 24, 2014
Imprint: Springer
Language: English

In this thesis, the focus is on the study of new catalytic properties of unsupported nanoporous metals in heterogeneous organic reactions under liquid-phase conditions. The author was the first to fabricate nanoporous copper with tunable nanoporosity and apply it for organic reactions. The catalyst can be reused up to ten times without loss of catalytic activity. In addition, the author developed the highly selective semihydrogenation of alkynes using nanoporous gold as a catalyst for the first time, affording Z-alkenes in 100% selectivity, which cannot be realized by traditional catalysts. All of the results described here will help readers to develop new catalytic performance of nanoporous metals for organic reactions.

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In this thesis, the focus is on the study of new catalytic properties of unsupported nanoporous metals in heterogeneous organic reactions under liquid-phase conditions. The author was the first to fabricate nanoporous copper with tunable nanoporosity and apply it for organic reactions. The catalyst can be reused up to ten times without loss of catalytic activity. In addition, the author developed the highly selective semihydrogenation of alkynes using nanoporous gold as a catalyst for the first time, affording Z-alkenes in 100% selectivity, which cannot be realized by traditional catalysts. All of the results described here will help readers to develop new catalytic performance of nanoporous metals for organic reactions.

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