Electronic Structure of Metal Phthalocyanines on Ag(100)

Nonfiction, Science & Nature, Science, Physics, Solid State Physics, Technology, Material Science
Cover of the book Electronic Structure of Metal Phthalocyanines on Ag(100) by Cornelius Krull, Springer International Publishing
View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart
Author: Cornelius Krull ISBN: 9783319026602
Publisher: Springer International Publishing Publication: November 19, 2013
Imprint: Springer Language: English
Author: Cornelius Krull
ISBN: 9783319026602
Publisher: Springer International Publishing
Publication: November 19, 2013
Imprint: Springer
Language: English

The application of molecules in technological devices hinges on the proper understanding of their behavior on metallic electrodes or substrates. The intrinsic molecular electronic and magnetic properties are modified at a metallic interface, and greatly depend on the atomic configuration of the molecule-metal bond. This poses certain problems, such as the lack of reproducibility in the transport properties of molecular junctions, but also offers the possibility to induce new charge and spin configurations that are only present at the interface. The results presented in this thesis address this issue, providing a comprehensive overview of the influence of molecule-metal and molecule-molecule interactions on the electronic and magnetic properties of molecules adsorbed on metallic substrates. Using metal-phthalocyanines (MePc), a commonly used metal-organic complex as a model system, each chapter explores different aspects of the interaction with silver surfaces: the local adsorption geometry, self-assembly, the modifications of the electronic and magnetic characteristics due to hybridization and charge transfer, and finally the manipulation of molecular charge and spin states by electron doping using alkali atoms moved with the STM tip.

View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart

The application of molecules in technological devices hinges on the proper understanding of their behavior on metallic electrodes or substrates. The intrinsic molecular electronic and magnetic properties are modified at a metallic interface, and greatly depend on the atomic configuration of the molecule-metal bond. This poses certain problems, such as the lack of reproducibility in the transport properties of molecular junctions, but also offers the possibility to induce new charge and spin configurations that are only present at the interface. The results presented in this thesis address this issue, providing a comprehensive overview of the influence of molecule-metal and molecule-molecule interactions on the electronic and magnetic properties of molecules adsorbed on metallic substrates. Using metal-phthalocyanines (MePc), a commonly used metal-organic complex as a model system, each chapter explores different aspects of the interaction with silver surfaces: the local adsorption geometry, self-assembly, the modifications of the electronic and magnetic characteristics due to hybridization and charge transfer, and finally the manipulation of molecular charge and spin states by electron doping using alkali atoms moved with the STM tip.

More books from Springer International Publishing

Cover of the book Regulation of Implantation and Establishment of Pregnancy in Mammals by Cornelius Krull
Cover of the book Decentralized Solutions for Developing Economies by Cornelius Krull
Cover of the book Intelligent Building Control Systems by Cornelius Krull
Cover of the book Development and Planning in Seven Major Coastal Cities in Southern and Eastern China by Cornelius Krull
Cover of the book The Networking of Chaperones by Co-chaperones by Cornelius Krull
Cover of the book From Molecules to Materials by Cornelius Krull
Cover of the book Dominant Elites in Latin America by Cornelius Krull
Cover of the book Constructing National Identity in Canadian and Australian Classrooms by Cornelius Krull
Cover of the book Non-Integer Order Calculus and its Applications by Cornelius Krull
Cover of the book GeNeDis 2014 by Cornelius Krull
Cover of the book Familial Mediterranean Fever by Cornelius Krull
Cover of the book Innovative Technologies in Everyday Life by Cornelius Krull
Cover of the book Geometric Continuum Mechanics and Induced Beam Theories by Cornelius Krull
Cover of the book Sociology of Exorcism in Late Modernity by Cornelius Krull
Cover of the book Learning and Collaboration Technologies. Designing Learning Experiences by Cornelius Krull
We use our own "cookies" and third party cookies to improve services and to see statistical information. By using this website, you agree to our Privacy Policy